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It'll have to be in the SKEL.
/etc/skel/Applications/Settings/Thunar/uca.xml

People can replace the contents of their current uca.xml file with the following to gain this functionality now.
/home/[USERNAME]/Applications/Settings/Thunar/uca.xml

<?xml encoding="UTF-8" version="1.0"?>
<actions>
<action>
<icon>Terminal</icon>
<name>Open Terminal Here</name>
<command>exo-open --working-directory %f --launch TerminalEmulator</command>
<description>Example for a custom action</description>
<patterns>*</patterns>
<directories/>
</action>
<action>
<icon>emblem-symbolic-link</icon>
<name>Mount PND</name>
<command>/usr/pandora/scripts/pnd_run.sh -p %f -m &amp;&amp; thunar /mnt/utmp/</command>
<description></description>
<patterns>*.pnd;*.PND</patterns>
<other-files/>
<text-files/>
</action>
<action>
<icon>gtk-jump-to-rtl</icon>
<name>Unmount PND</name>
<command>/usr/pandora/scripts/pnd_run.sh -p %f -u</command>
<description></description>
<patterns>*.pnd;*.PND</patterns>
<other-files/>
<text-files/>
</action>
</actions>